Triethylamine → HCID 54017040, compound

HRID 1448077Notes

Reaction equation

HRID 1448077 reaction equation
[N+:1]([C:4]([CH3:9])([CH3:8])[CH:5]=[N:6][OH:7])([O-:3])=[O:2].[CH3:10][N:11]([S:15][C:16]([CH3:23])([C:18](=[O:22])[CH:19]([CH3:21])[CH3:20])[CH3:17])[C:12](F)=[O:13].C(N(CC)CC)C>O1CCOCC1>[CH3:10][N:11]([S:15][C:16]([CH3:17])([C:18](=[O:22])[CH:19]([CH3:20])[CH3:21])[CH3:23])[C:12]([O:7][N:6]=[CH:5][C:4]([N+:1]([O-:3])=[O:2])([CH3:9])[CH3:8])=[O:13]

Participants

5

Reactant 3

HCID 8471TriethylamineHCID 54533821HCID 54533821, compoundHCID 86736740HCID 86736740, compound

Product 1

HCID 54017040HCID 54017040, compoundYield 7.8%

Reagents, catalysts & solvents 1

HCID 312751,4-DioxaneSolvent

Procedure

Prepared as in Example 1 by reacting 2.78 g (0.021 m) of 2-nitro-2-methylpropionaldoxime, 5.0 g (0.21 m) of N-methyl-N-(2,4-dimethyl-3-oxo-2-pentanesulfenyl)carbamoyl fluoride and 2.13 g (0.021 m) of triethylamine in 50 ml of dioxane. The product was purified by column chromatography to yield 0.55 g of an oil.

Workup

  1. customPrepared as in Example 1
  2. customThe product was purified by column chromatography

Sources & evidence

ORD record
ord-be442cbe398b4a09bd8b9f6bc50d3a81
Source dataset
uspto-grants-1979_12
Patent number
US04179514

Reaction notes

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