Methyl Chloride → HCID 20351236, compound

HRID 1448945Notes

Reaction equation

HRID 1448945 reaction equation
[CH2:1]([P:9]([CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19])[CH2:10][CH3:11])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[CH3:20][Cl:21]>>[Cl-:21].[CH2:12]([P+:9]([CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8])([CH2:10][CH3:11])[CH3:20])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19]

Participants

3

Reactant 2

HCID 6327Methyl ChlorideHCID 22497600HCID 22497600, compound

Product 1

HCID 20351236HCID 20351236, compound

Procedure

Into 14.4 g (0.05 m) of dioctyl ethyl phosphine, placed in the bubbler reactor described in Example 2, methyl chloride was introduced at 130° C. for 4 hours. The degree of weight gain observed corresponded to a quantitative formation of the desired product; a colorless, waxy solid at room temperature. In the nmr spectrum of this product, the α-meythyl doublet appears at 1.93 ppm (JP-C 14 cps).

Workup

  1. additionwas introduced at 130° C. for 4 hours

Sources & evidence

ORD record
ord-4cb773b668114df29a1b317fbb2a8713
Source dataset
uspto-grants-1980_02
Patent number
US04188380

Reaction notes

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