Dicyclopentadiene → HCID 43754984, compound

HRID 1451136Notes

Reaction equation

HRID 1451136 reaction equation
[CH2:1]1[CH:5]2[CH:6]3[CH:10]=[CH:9][CH:8]([CH:4]2C=C1)[CH2:7]3.C([NH:14][C:15]([CH3:18])([CH3:17])[CH3:16])C=C>>[C:15]([NH:14][CH2:1][CH:5]1[CH2:4][CH:8]2[CH2:7][CH:6]1[CH:10]=[CH:9]2)([CH3:18])([CH3:17])[CH3:16]

Participants

3

Reactant 2

HCID 6492DicyclopentadieneHCID 566539N-tert-Butylallylamine

Product 1

HCID 43754984HCID 43754984, compoundYield 64.7%

Conditions

Temperature
185 °C

Procedure

5-(t-butylanfinomethyl)norbomene. 14 g of dicyclopentadiene and 60 g of the N-allyl-N-t-butylamine were placed neat in a Parr High-Pressure Reactor. The reaction was heated to 185° C. with stirring for 15 h. The reaction was then cooled down and the reaction solution was distilled under vacuum (0.5 torr). The desired product distilled over at 35°-36 ° C. 24.6 g of product was collected in this way (64.7% yield).

Workup

  1. temperatureThe reaction was then cooled down
  2. distillationthe reaction solution was distilled under vacuum (0.5 torr)
  3. distillationThe desired product distilled over at 35°-36 ° C
  4. custom24.6 g of product was collected in this way (64.7% yield)

Sources & evidence

ORD record
ord-0f41358b02a840529c19d67bdc0593f9
Source dataset
uspto-grants-1997_02
Patent number
US05603985

Reaction notes

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