Hydrogen Peroxide → HCID 178506628, compound

HRID 1457080Notes

Reaction equation

HRID 1457080 reaction equation
[N:1]1[CH:6]=[CH:5][CH:4]=[CH:3][C:2]=1[C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][N:8]=1.[K].[O-2].[O-2].[O-2].[O-2].[O-2].[V+5:19].[V+5].[OH-].[K+:22].OO.N1C=CC=[CH:27][C:26]=1C1C=CC=CN=1.[K]>O.C(O)C>[V+5:19].[N:1]1[C:2]2[C:3](=[CH:26][CH:27]=[C:12]3[C:7]=2[N:8]=[CH:9][CH:10]=[CH:11]3)[CH:4]=[CH:5][CH:6]=1.[K+:22]

Participants

9

Reactant 6

HCID 784Hydrogen Peroxide2×HCID 14742,2'-BipyridineHCID 14797Potassium HydroxideHCID 5462222PotassiumHCID 86753407HCID 86753407, compoundHCID 178419084HCID 178419084, compound

Product 1

HCID 178506628HCID 178506628, compound

Reagents, catalysts & solvents 2

HCID 702EthanolSolventHCID 962WaterSolvent

Procedure

For potassium (2,2'-bipyridine) oxodiperoxovanadium (V), vanadium pentoxide (0.91 g) and potassium hydroxide (0.65 g) are dissolved in water (10 ml), cooled, and, if necessary, the dissolution is completed with a small amount of hydrogen peroxide. To the clear, cooled solution, hydrogen peroxide (10 ml) and 2,2'-bipyridine (1.6 g) dissolved in ethanol (7-8 ml) are added. Pure crystals are obtained as described for the analogous oxalato-derivative of potassium. Potassium (1,10-phenanthroline) vanadium (V) can be obtained similarly.

Workup

  1. temperaturecooled
  2. dissolutionif necessary, the dissolution
  3. additionare added
  4. customPure crystals are obtained

Sources & evidence

ORD record
ord-f8e7b856c27d45e9a4df8a377a04614e
Source dataset
uspto-grants-1998_12
Patent number
US05846998

Reaction notes

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