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HRID1460615

反应详情

EQUATION

反应方程式

HRID 1460615 的结构方程式

REACTANTS

反应物

3
结构：[H-].[Na+]
HCID24758

Sodium hydride

HNa

结构：CC1(C)Oc2ccc(C#N)cc2[C@@H](OC2=CC(=O)CC2)[C@@H]1O
HCID129348

3-Hydroxy-2,2-dimethyl-4-[(3-oxocyclopent-1-en-1-yl)oxy]-3,4-dihydro-2H-1-benzopyran-6-carbonitrile

C17H17NO4

结构：NC1=CC(=O)OC1
HCID13374861

未命名化合物

PRODUCTS

生成物

1
结构：CC1(C)Oc2ccc(C#N)cc2[C@@H](NC2=CC(=O)OC2)[C@@H]1O
HCID14301306

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CS(C)=O
溶剂HCID679

Dimethyl sulfoxide

C2H6OS

PROCEDURE

实验过程

34,5 mg of the epoxide of example 1 and 17 mg of 4-Amino-2-(5H)-furanone (CAS 92089-08-2) are reacted analogously to example 5 with sodium hydride in dimethylsulfoxide. The usual working up yields yellowish crystalls of the title compound having a m.p. of 182° C. (from ethanol/dichloromethane, decomposition).