Potassium Carbonate → HCID 178449885, compound

HRID 1461567Notes

Reaction equation

HRID 1461567 reaction equation
[C-:1]1([C:6]([NH:8][NH:9][C:10]([CH3:13])([CH3:12])[CH3:11])=[O:7])[CH:5]=[CH:4][CH:3]=[CH:2]1.[CH-:14]1[CH:18]=[CH:17][CH:16]=[CH:15]1.[Fe+2:19].C(=O)([O-])[O-].[K+].[K+].[Br:26][C:27]1[CH:35]=[CH:34][CH:33]=[CH:32][C:28]=1[C:29](Cl)=[O:30]>C1(C)C=CC=CC=1.O>[C-:1]1([C:6]([NH:8][N:9]([C:29](=[O:30])[C:28]2[CH:32]=[CH:33][CH:34]=[CH:35][C:27]=2[Br:26])[C:10]([CH3:13])([CH3:12])[CH3:11])=[O:7])[CH:2]=[CH:3][CH:4]=[CH:5]1.[CH-:14]1[CH:18]=[CH:17][CH:16]=[CH:15]1.[Fe+2:19]

Participants

6

Reactant 3

HCID 11430Potassium CarbonateHCID 235422-Bromobenzoyl chlorideHCID 178449886HCID 178449886, compound

Product 1

HCID 178449885HCID 178449885, compound

Reagents, catalysts & solvents 2

HCID 962WaterSolventHCID 1140TolueneSolvent2×

Procedure

To a stirred mixture of N-ferrocenoyl-N'-tert-butylhydrazine (0.5 g, 1.65 mmoL) in toluene (10 mL), and potassium carbonate (0.5 g, 3.62 mmoL) in water (5 ml) was added a solution of 2-bromobenzoyl chloride (0.5 g, 1.82 mmoL) in toluene (5 mL) dropwise in 15 minutes. The resulting mixture was stirred vigorously for two hours and the solid was filtered, washed with water, ethyl ether and dried to afford product as a bright yellow solid, melting point 175° C.

Workup

  1. filtrationthe solid was filtered
  2. washwashed with water, ethyl ether
  3. customdried
  4. customto afford product as a bright yellow solid, melting point 175° C.

Sources & evidence

ORD record
ord-be4c25185530402aa86057bebafaa19c
Source dataset
uspto-grants-1991_12
Patent number
US05075471

Reaction notes

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