Triethylamine → HCID 19742191, compound

HRID 1461618Notes

Reaction equation

HRID 1461618 reaction equation
[CH2:1]([N:5]1[C:9]2([CH2:14][O:13][P:12](Cl)[O:11][CH2:10]2)[CH2:8][O:7][P:6]1Cl)[CH:2]([CH3:4])[CH3:3].[CH2:17]([SH:35])[CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH3:34].C(N([CH2:41][CH3:42])CC)C>C1(C)C=CC=CC=1>[CH2:1]([N:5]1[C:9]2([CH2:14][O:13][P:12]([S:35][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH3:34])[O:11][CH2:10]2)[CH2:8][O:7][P:6]1[S:35][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:41][CH3:42])[CH:2]([CH3:4])[CH3:3]

Participants

5

Reactant 3

HCID 8471TriethylamineHCID 179051-OctadecanethiolHCID 19742171HCID 19742171, compound

Product 1

HCID 19742191HCID 19742191, compoundYield 30.9%

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

The procedure of Example 10 is repeated using 8.72 g (28.5 mmol) of 1-isobutyl-2,8-dichloro-3,7,9-trioxa-1-aza-2,8-diphosphaspiro[4.5]decane, 16.33 g (57 mmol) of n-octadecyl mercaptan and 8.74 mL (63 mmol) of triethylamine in 200 mL of toluene. A white solid (7.11 g) is isolated. The product is identified by mass spectroscopy: m/z=805.

Sources & evidence

ORD record
ord-a20cca4e709d4fa4886b459d9c4e8095
Source dataset
uspto-grants-1991_12
Patent number
US05075482

Reaction notes

Loading…