Benzene → HCID 131717132, compound

HRID 1461626Notes

Reaction equation

HRID 1461626 reaction equation
C1C=CC=CC=1.[CH3:7][C:8]([C:10]([O:12][CH3:13])=[O:11])=[CH2:9].[CH2:14]1[N:16]([P:17]2([N:33]3[CH2:35][CH2:34]3)[N:22]=[S:21]([N:24]3[CH2:26][CH2:25]3)(=[O:23])[N:20]=[P:19]([N:30]3[CH2:32][CH2:31]3)([N:27]3[CH2:29][CH2:28]3)[N:18]=2)[CH2:15]1>C(Cl)C(Cl)Cl.O>[CH2:29]1[N:27]([P:19]2([N:30]3[CH2:32][CH2:31]3)[N:20]=[S:21]([N:24]3[CH2:25][CH2:26]3)(=[O:23])[N:22]=[P:17]([N:16]3[CH2:14][CH2:15]3)([N:33]3[CH2:35][CH2:34]3)[N:18]=2)[CH2:28]1.[CH3:9][C:8]([C:10]([O:12][CH3:13])=[O:11])=[CH2:7]

Participants

6

Reactant 3

HCID 241Benzene2×HCID 6658Methyl MethacrylateHCID 72601Pentazirinocyclodiphosphathiazene

Product 1

HCID 131717132HCID 131717132, compound

Reagents, catalysts & solvents 2

HCID 962WaterSolvent2×HCID 65741,1,2-TrichloroethaneSolvent

Procedure

A benzene solution in which SOAZ was dissolved in a concentration of 0.2 mg/ml and a solution obtained by dissolving PMMA (produced by of Polyscience Co.; syndiotactic; molecular weight: 100,000) in a mixed solution of trichloroethane:benzene=1:9 (V/V) in a concentration of 0.2 mg/ml, were appropriately mixed so as to give the desired mixing ratio, and thereafter the resulting mixed solution was spread on pure water of 20° C. in water temperature to form an SOAZ-PMMA mixed monomolecular film on the water surface. After removal of the solvent by evaporation, the surface pressure of the monomolecular film thus formed was raised up to 20 mN/m. While keeping constant the surface pressure, a substrate provided with the lower electrode 2 (Cr/Au), prepared in the same manner as Example 1, was gently put in water at a rate of 5 mm/min in the direction traversing the water surface, and thereafter subsequently gently drawn up at a rate of 5 mm/min, thus building up a two-layer Y-type mixed monomolecular film. Such operations were repeated several times to form a 12-layer mixed built-up film, thus providing the organic insulating layer 3.

Workup

  1. customa solution obtained
  2. customto give the
  3. additiondesired mixing ratio
  4. additionthe resulting mixed solution

Sources & evidence

ORD record
ord-9cfda1cd2c6740b79f63acf31b8b8a26
Source dataset
uspto-grants-1991_12
Patent number
US05075738

Reaction notes

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