Tetrabutylammonium Hydroxide → HCID 86739521, compound

HRID 1462128Notes

Reaction equation

HRID 1462128 reaction equation
[OH:1][C:2]1[CH:7]=[CH:6][C:5]([CH2:8][S:9]([CH2:12][C:13]2[CH:18]=[CH:17][C:16]([OH:19])=[C:15]([N+:20]([O-:22])=[O:21])[CH:14]=2)(=[O:11])=[O:10])=[CH:4][C:3]=1[N+:23]([O-:25])=[O:24].[OH-].[CH2:27]([N+:31]([CH2:40][CH2:41][CH2:42][CH3:43])([CH2:36][CH2:37][CH2:38][CH3:39])[CH2:32][CH2:33][CH2:34][CH3:35])[CH2:28][CH2:29][CH3:30]>C(O)C>[CH2:40]([N+:31]([CH2:27][CH2:28][CH2:29][CH3:30])([CH2:32][CH2:33][CH2:34][CH3:35])[CH2:36][CH2:37][CH2:38][CH3:39])[CH2:41][CH2:42][CH3:43].[OH:19][C:16]1[CH:17]=[CH:18][C:13]([CH2:12][S:9]([CH2:8][C:5]2[CH:6]=[CH:7][C:2]([OH:1])=[C:3]([N+:23]([O-:25])=[O:24])[CH:4]=2)(=[O:11])=[O:10])=[CH:14][C:15]=1[N+:20]([O-:22])=[O:21]

Participants

4

Reactant 2

HCID 2723671Tetrabutylammonium HydroxideHCID 86739519HCID 86739519, compound

Product 1

HCID 86739521HCID 86739521, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

To a solution of 13.5 g of 4-hydroxy-3-nitrophenylmethylsulfone in 100 ml of ethanol are added 41 g of a 40% aqueous tetrabutylammonium hydroxide solution. The resultant deep yellow solution is evaporated in a rotovap to give 28 g of yellow crystal product with a melting point of 98°-100° C.

Workup

  1. customThe resultant deep yellow solution is evaporated in a rotovap

Sources & evidence

ORD record
ord-7a0fe596c81b4d58bac5961b58e8c73b
Source dataset
uspto-grants-1984_07
Patent number
US04459152

Reaction notes

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