Phenolate Sodium → HCID 53693383, compound

HRID 1462652Notes

Reaction equation

HRID 1462652 reaction equation
[C:1]1([O-:7])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Na+].[Cl:9][C:10](Cl)=[CH:11][C:12]([CH3:16])([CH3:15])[CH:13]=[CH2:14]>CN1CCCC1=O>[Cl:9][CH:10]=[C:11]([O:7][C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1)[C:12]([CH3:16])([CH3:15])[CH:13]=[CH2:14]

Participants

4

Reactant 2

HCID 4445035Phenolate SodiumHCID 13089648HCID 13089648, compound

Product 1

HCID 53693383HCID 53693383, compoundYield 92%

Reagents, catalysts & solvents 1

HCID 13387N-methyl-2-pyrrolidoneSolvent

Procedure

23.2 g (0.2 mol) of sodium phenolate and 16.5 g (0.1 mol) of 1,1-dichloro-3,3-dimethyl-1,4-pentadiene are heated to 180° C. in 100 ml of N-methylpyrrolidone, during the course of 10 hours. The working-up corresponding to Example A1(a) yields 20.5 g (92% of theory) of 1-chloro-3,3-dimethyl-2-phenoxy-1,4-pentadiene.

Sources & evidence

ORD record
ord-39207f778b9a466097ad78158c62bbf9
Source dataset
uspto-grants-1984_07
Patent number
US04460793

Reaction notes

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