Hydrochloric Acid → HCID 73678921, compound

HRID 1462674Notes

Reaction equation

HRID 1462674 reaction equation
[CH3:1][CH:2]1[CH2:13][CH:12]=[CH:11][CH2:10][CH2:9][CH:8]=[CH:7][CH2:6][CH:5]([CH:14]([CH:16]=[CH:17][CH3:18])[CH3:15])[N:4]=[CH:3]1.S(O)(O)(=O)=O.[NH2:24][OH:25].Cl>O>[CH3:1][CH:2]([CH2:13][CH:12]=[CH:11][CH2:10][CH2:9][CH:8]=[CH:7][CH2:6][CH:5]([CH:14]([CH:16]=[CH:17][CH3:18])[CH3:15])[NH2:4])[CH:3]=[N:24][OH:25]

Participants

5

Reactant 3

HCID 313Hydrochloric AcidHCID 159255Hydroxylamine, sulfate (1:1)HCID 54073519HCID 54073519, compound

Product 1

HCID 73678921HCID 73678921, compoundYield 195.2%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

The procedure is carried out in the manner described in Example 1(b) but with the use of 122.7 g (0.5 mol) of 3-methyl-12-(3-penten-2-yl)-1-aza-1,5,9-cyclododecatriene, 41.1 g (0.25 mol) of hydroxylamine sulfate, 50 ml of concentrated hydrochloric acid and 250 ml of water. There is obtained on further processing 135.9 g (0.488 mol) of 2-methyl-11-(3-penten-2-yl)-11-amino-undeca-4,8-dienal-oxime; yield 97.6% of theory; nD20 =1.5091.

Sources & evidence

ORD record
ord-5f15820afa754b8cb4e4c6100fa35e6e
Source dataset
uspto-grants-1984_07
Patent number
US04460790

Reaction notes

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