Iodoethane → 2(1H)-Quinolinone, 1-ethyl-

HRID 1463829Notes

Reaction equation

HRID 1463829 reaction equation
I[C:2]1[CH:3]=[C:4]2[C:9](=[CH:10][CH:11]=1)[N:8]([CH2:12][CH3:13])[C:7](=[O:14])[CH:6]=[CH:5]2.IC1C=C2C(=CC=1)N(C)C(=O)C=C2.C(I)C>CI>[CH2:12]([N:8]1[C:9]2[C:4](=[CH:3][CH:2]=[CH:11][CH:10]=2)[CH:5]=[CH:6][C:7]1=[O:14])[CH3:13]

Participants

5

Reactant 3

HCID 6340IodoethaneHCID 19088458HCID 19088458, compoundHCID 22413835HCID 22413835, compound

Product 1

HCID 1046032(1H)-Quinolinone, 1-ethyl-

Reagents, catalysts & solvents 1

HCID 6328Methyl iodideSolvent

Procedure

The 1,2-dihydro-6-iodo-1-ethylquinolin-2-one used as a starting material was obtained using a similar procedure to that described in the portion of Example 1 which is concerned with the preparation of the starting material 1,2-dihydro-6-iodo-1-methylquinolin-2-one, except that ethyl iodide was used in place in methyl iodide. There were thus obtained in turn 1,2-dihydro-1-ethylquinolin-2-one, m.p. 52°-54° C., and the required starting material as an oil.

Workup

  1. customwas obtained

Sources & evidence

ORD record
ord-4d77e357587f4bdbadfa3a99ec7db883
Source dataset
uspto-grants-1994_04
Patent number
US05302594

Reaction notes

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