Hydride → HCID 19917128, compound

HRID 1464776Notes

Reaction equation

HRID 1464776 reaction equation
[S:1]1[CH:5]=[CH:4][C:3]([C:6]2[CH:7]=[C:8]([CH:19]=[CH:20][CH:21]=2)[O:9][CH2:10][CH2:11][O:12][CH:13]([CH3:18])[C:14](OC)=[O:15])=[CH:2]1.[Li].[H-]>O1CCCC1>[S:1]1[CH:5]=[CH:4][C:3]([C:6]2[CH:7]=[C:8]([CH:19]=[CH:20][CH:21]=2)[O:9][CH2:10][CH2:11][O:12][CH:13]([CH3:18])[CH2:14][OH:15])=[CH:2]1

Participants

5

Reactant 3

HCID 166653HydrideHCID 3028194LithiumHCID 19917015HCID 19917015, compound

Product 1

HCID 19917128HCID 19917128, compoundYield 99.1%

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

0.20 g of the resulting ester compound was dissolved in 5 ml of tetrahydrofuran, and reduced as in Referential Example 31 with 25 mg of lithium alminum hydride to give 0.18 g of the captioned compound as a colorless oil.

Sources & evidence

ORD record
ord-ed26bd89c5cd478c909657717874124e
Source dataset
uspto-grants-1994_04
Patent number
US05306728

Reaction notes

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