HRID1465687

反应详情

EQUATION

反应方程式

HRID 1465687 的结构方程式

AUXILIARIES

试剂、催化剂与溶剂

1

PROCEDURE

实验过程

To the crude (R)-tert-butyl 3-(1-(3-(pyridin-4-yl)-1-trityl-1H-indazol-5-yl)-1H-1,2,3-triazol-4-yl)piperidine-1-carboxylate dissolved in CH2Cl2 (30 mL) was added TFA (2 mL and Et3SiH (0.2 mL) and stirred at room temperature overnight under a stream of nitrogen. Evaporated the solvent and column purified (10% MeOH in CH2Cl2) to give the (R)-5-(4-(piperidin-3-yl)-1H-1,2,3-triazol-1-yl)-3-(pyridin-4-yl)-1H-indazole (0.61 g).

WORKUP

后处理

  1. customEvaporated the solvent and column
  2. custompurified (10% MeOH in CH2Cl2)