Acetate → 4-(2-Phenylethenyl)-1-benzothiophene

HRID 147499Notes

Reaction equation

HRID 147499 reaction equation
[Br:1][c:2]1[cH:3][cH:4][cH:5][c:6]2[s:7][cH:8][cH:9][c:10]12.[CH2:11]=[CH:12][c:13]1[cH:14][cH:15][cH:16][cH:17][cH:18]1.[CH3:19][CH2:20][N:21]([CH2:22][CH3:23])[CH2:24][CH3:25].[CH3:26][c:27]1[cH:28][cH:29][cH:30][cH:31][c:32]1[P:33]([c:34]1[cH:35][cH:36][cH:37][cH:38][c:39]1[CH3:40])[c:41]1[cH:42][cH:43][cH:44][cH:45][c:46]1[CH3:47].[CH3:48][C:49]#[N:50].[CH3:51][CH2:52][O:53][CH2:54][CH3:55].[O-:57][C:58]([CH3:59])=[O:60].[O-:61][C:62]([CH3:63])=[O:64].[Pd+2:56]>>[c:2]1([CH:11]=[CH:12][c:13]2[cH:14][cH:15][cH:16][cH:17][cH:18]2)[cH:3][cH:4][cH:5][c:6]2[s:7][cH:8][cH:9][c:10]12

Participants

9

Reactant 8

HCID 175Acetate2×HCID 3283Diethyl EtherHCID 6342AcetonitrileHCID 7501StyreneHCID 8471TriethylamineHCID 80271Tri-o-tolylphosphineHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 120942084-Bromobenzo[b]thiophene

Product 1

HCID 687157454-(2-Phenylethenyl)-1-benzothiophene

Sources & evidence

ORD record
ord-e659382157d844f886f6813ba648ad28
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (9/10)

Reaction notes

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