1-Pentanol → HCID 19938763, compound

Temperature

90 °C

Into a pressure vessel 1-pentanol (109 μL, 1 mmol, 1 eq) was added and diluted with cyclohexane (1.080 mL, 10 mmol, 10 eq). To this stirring solution was added 1 mol % of a stock solution of {[Cl2NN]Cu}2(benzene) from the catalyst stock solution described in Example 4 (200 μL=0.01 mmol). After adding of tert-butyl peroxide (220 μL, 1.2 mmol), the pressure vessel was sealed and heated to 90° C. for 24 hr. The catalyst was separated by exposing the mixture to air and filtering through Celite®. After removing cyclohexane under vacuum, the residue was analyzed by 1H NMR and GC/MS to determine the yield and consumption of starting materials. 1H NMR Yield: 40%.

1. customthe pressure vessel was sealed
2. customThe catalyst was separated
3. filtrationfiltering through Celite®
4. customAfter removing cyclohexane under vacuum
5. customyield
6. customconsumption of starting materials

ORD record

ord-a545e88ee6a44924a59d0c5fa796015a

Source dataset

uspto-grants-2016_08

DOI

10.6084/m9.figshare.5104873.v1

Patent number

US09416080B2