Pyrrolidine → 4-Bromo-N-[methyl(oxo)pyrrolidin-1-yl-lambda6-sulfanylidene]aniline

HRID 1485617Notes

Reaction equation

[Br:1][C:2]1[CH:7]=[CH:6][C:5]([NH:8][S:9]([CH3:11])=[O:10])=[CH:4][CH:3]=1.[NH:12]1[CH2:16][CH2:15][CH2:14][CH2:13]1>>[Br:1][C:2]1[CH:7]=[CH:6][C:5]([N:8]=[S:9]([CH3:11])(=[O:10])[N:12]2[CH2:16][CH2:15][CH2:14][CH2:13]2)=[CH:4][CH:3]=1

Participants

Reactant 2

HCID 31268Pyrrolidine

HCID 14195208N-(4-Bromophenyl)methanesulfinamide

Product 1

HCID 1188639314-Bromo-N-[methyl(oxo)pyrrolidin-1-yl-lambda6-sulfanylidene]aniline

Procedure

The title compound is prepared from N-(4-bromophenyl)methanesulfinamide and pyrrolidine following a procedure analogous to that described for Intermediate 3 (Step 2). LC (method 1): tR=0.99 min; Mass spectrum (ESI+): m/z=303, 305 [M+H]+.

Sources & evidence

ORD record: ord-01ee8290829c463a990902f8340a016b
Source dataset: uspto-grants-2016_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US09422312B2

Reaction notes

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