p-Toluenesulfonic acid → 1-Propanol, 3-(triethoxysilyl)-, 1-acetate

HRID 1489885Notes

Reaction equation

HRID 1489885 reaction equation
C1(C)C=CC(S(O)(=O)=O)=CC=1.[C:12]([O:16][CH2:17][CH2:18][CH2:19][Si:20]([O:27][CH2:28][CH3:29])([O:24][CH2:25][CH3:26])[O:21][CH2:22][CH3:23])(=[O:15])[CH:13]=C>>[C:12]([O:16][CH2:17][CH2:18][CH2:19][Si:20]([O:24][CH2:25][CH3:26])([O:21][CH2:22][CH3:23])[O:27][CH2:28][CH3:29])(=[O:15])[CH3:13]

Participants

3

Reactant 2

HCID 6101p-Toluenesulfonic acidHCID 111193523-(Triethoxysilyl)propyl prop-2-enoate

Product 1

HCID 109783391-Propanol, 3-(triethoxysilyl)-, 1-acetateYield 41%

Procedure

The same procedure as in Example 1 was followed to conduct a reaction, except that p-toluenesulfonic acid was used in place of Ti(OBu)4. After completion of the reaction, the reaction product was analyzed by GC. As a result, it was thus found that triethoxysilylpropyl acrylate as the objective compound had been obtained in a yield of 41% (in terms of triethoxysilylpropyl acetate).

Workup

  1. customa reaction
  2. customAfter completion of the reaction

Sources & evidence

ORD record
ord-4b2e15072b7144e395dec32d4c970606
Source dataset
uspto-grants-1997_10
Patent number
US05679821

Reaction notes

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