2-Methylbenzothiazole → HCID 72221079, compound

HRID 1490450Notes

Reaction equation

HRID 1490450 reaction equation
Cc1nc2ccccc2s1>C1=CCCC=CCC1.C1=CCCC=CCC1.C1CCOC1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.C[OH2+].C[OH2+].Cc1cnc2c(ccc3c(C)c(C)cnc32)c1C.[Ir].[Ir]>Cc1nc2ccc(B3OC(C)(C)C(C)(C)O3)cc2s1.Cc1nc2cccc(B3OC(C)(C)C(C)(C)O3)c2s1

Participants

7

Reactant 1

HCID 84462-Methylbenzothiazole

Product 2

HCID 208163372-Methylbenzo[d]thiazol-6-ylboronic acid pinacol esterYield 9%HCID 72221079HCID 72221079, compoundYield 24%

Reagents, catalysts & solvents 4

HCID 742653,4,7,8-Tetramethyl-1,10-phenanthrolineReagentHCID 2733548Bis(pinacolato)diboraneReagentHCID 76001521Bis(1,5-cyclooctadiene)dimethoxydiiridiumCatalystHCID 8028TetrahydrofuranSolvent

Conditions

Temperature
50 °C

Sources & evidence

ORD record
ord-4f3c78f3989945ffb77525be1fcde576
Source dataset
Borylation dataset from Roche

Reaction notes

Loading…