2,7-Dimethyl-1H-benzo[d]imidazole → HCID 130141602, compound

HRID 1490456Notes

Reaction equation

HRID 1490456 reaction equation
Cc1nc2c(C)cccc2[nH]1>C1=CCCC=CCC1.C1=CCCC=CCC1.C1CCOC1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.C[OH2+].C[OH2+].Cc1cnc2c(ccc3c(C)c(C)cnc32)c1C.[Ir].[Ir]>Cc1nc2c(C)cc(B3OC(C)(C)C(C)(C)O3)cc2[nH]1

Participants

6

Reactant 1

HCID 41559752,7-Dimethyl-1H-benzo[d]imidazole

Product 1

HCID 130141602HCID 130141602, compoundYield 72%

Reagents, catalysts & solvents 4

HCID 742653,4,7,8-Tetramethyl-1,10-phenanthrolineReagentHCID 2733548Bis(pinacolato)diboraneReagentHCID 76001521Bis(1,5-cyclooctadiene)dimethoxydiiridiumCatalystHCID 8028TetrahydrofuranSolvent

Conditions

Temperature
80 °C

Sources & evidence

ORD record
ord-7a670851c07147a78d5a21be7c00b207
Source dataset
Borylation dataset from Roche

Reaction notes

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