4-Chloro-2-methyl-1H-benzo[d]imidazole → HCID 130754092, compound

HRID 1490459Notes

Reaction equation

HRID 1490459 reaction equation
Cc1nc2c(Cl)cccc2[nH]1>C1=CCCC=CCC1.C1=CCCC=CCC1.C1CCOC1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.C[OH2+].C[OH2+].Cc1cnc2c(ccc3c(C)c(C)cnc32)c1C.[Ir].[Ir]>Cc1nc2c(Cl)cc(B3OC(C)(C)C(C)(C)O3)cc2[nH]1

Participants

6

Reactant 1

HCID 14848974-Chloro-2-methyl-1H-benzo[d]imidazole

Product 1

HCID 130754092HCID 130754092, compoundYield 84%

Reagents, catalysts & solvents 4

HCID 742653,4,7,8-Tetramethyl-1,10-phenanthrolineReagentHCID 2733548Bis(pinacolato)diboraneReagentHCID 76001521Bis(1,5-cyclooctadiene)dimethoxydiiridiumCatalystHCID 8028TetrahydrofuranSolvent

Conditions

Temperature
80 °C

Sources & evidence

ORD record
ord-c9374e037c174865a5b48228a7615cb6
Source dataset
Borylation dataset from Roche

Reaction notes

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