Toluene → 4,4,5,5-Tetramethyl-2-(m-tolyl)-1,3,2-dioxaborolane

HRID 1490646Notes

Reaction equation

HRID 1490646 reaction equation
Cc1ccccc1>C1CCOC1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.Cc1cc2[n]3->[Co+3]([BH-]4OC(C)(C)C(C)(C)O4)([PH](C(C)C)(C(C)C)C2)[PH](C(C)C)(C(C)C)Cc3c1>Cc1cccc(B2OC(C)(C)C(C)(C)O2)c1

Participants

5

Reactant 1

HCID 1140Toluene

Product 1

HCID 27605984,4,5,5-Tetramethyl-2-(m-tolyl)-1,3,2-dioxaborolaneYield 27%

Reagents, catalysts & solvents 3

HCID 2733548Bis(pinacolato)diboraneReagentHCID 178422272HCID 178422272, compoundCatalystHCID 8028TetrahydrofuranSolvent

Conditions

Temperature
80 °C

Sources & evidence

ORD record
ord-569e06f9c9914e7fa68d69361f4213d5
Source dataset
Borylation dataset from Roche

Reaction notes

Loading…