2,3-Diethyl 2,3-pyridinedicarboxylate → HCID 178468562, compound

HRID 1490707Notes

Reaction equation

HRID 1490707 reaction equation
CCOC(=O)c1cccnc1C(=O)OCC>C1=CCCC=CCC1.C1=CCCC=CCC1.C1CCOC1.CC(C)(C)c1ccnc(-c2cc(C(C)(C)C)ccn2)c1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.C[OH2+].C[OH2+].[Ir].[Ir]>CCOC(=O)c1cc(B2OC(C)(C)C(C)(C)O2)cnc1C(=O)OCC

Participants

6

Reactant 1

HCID 108895172,3-Diethyl 2,3-pyridinedicarboxylate

Product 1

HCID 178468562HCID 178468562, compoundYield 95%

Reagents, catalysts & solvents 4

HCID 2733548Bis(pinacolato)diboraneReagentHCID 42491874,4'-Di-tert-butyl-2,2'-bipyridylReagentHCID 76001521Bis(1,5-cyclooctadiene)dimethoxydiiridiumCatalystHCID 8028TetrahydrofuranSolvent

Conditions

Temperature
80 °C

Sources & evidence

ORD record
ord-27838b73bcaf4b6cbba13d6cfac1f907
Source dataset
Borylation dataset from Roche

Reaction notes

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