Benzoic acid, 3,5-dihydroxy-, ethyl ester → HCID 178469298, compound

HRID 1490727Notes

Reaction equation

HRID 1490727 reaction equation
CCOC(=O)c1cc(O)cc(O)c1>C1=CCCC=CCC1.C1=CCCC=CCC1.C1CCOC1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.CC1(C)OBOC1(C)C.C[OH2+].C[OH2+].O=c1ccc2cccc(-c3ccc(-c4ccccn4)nc3)c2[nH]1.[Ir].[Ir]>CCOC(=O)c1cc(O)c(B2OC(C)(C)C(C)(C)O2)c(O)c1

Participants

7

Reactant 1

HCID 20098Benzoic acid, 3,5-dihydroxy-, ethyl ester

Product 1

HCID 178469298HCID 178469298, compoundYield 71%

Reagents, catalysts & solvents 5

HCID 2733548Bis(pinacolato)diboraneReagentHCID 27347684,4,5,5-Tetramethyl[1,3,2]dioxaborolaneReagentHCID 1646813858-([2,2'-bipyridin]-5-yl)quinolin-2(1H)-oneReagentHCID 76001521Bis(1,5-cyclooctadiene)dimethoxydiiridiumCatalystHCID 8028TetrahydrofuranSolvent

Conditions

Temperature
120 °C

Sources & evidence

ORD record
ord-f054326cb05240c7b589fa10b3b54c57
Source dataset
Borylation dataset from Roche

Reaction notes

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