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HRID1490929

反应详情

EQUATION

反应方程式

HRID 1490929 的结构方程式

REACTANTS

反应物

1
结构：Cc1ccccc1Cl
HCID7238

2-Chlorotoluene

C7H7Cl

PRODUCTS

生成物

2
结构：Cc1cc(B2OC(C)(C)C(C)(C)O2)ccc1Cl
HCID3767641

1,3,2-Dioxaborolane, 2-(4-chloro-3-methylphenyl)-4,4,5,5-tetramethyl-

C13H18BClO2

收率 34%
结构：Cc1ccc(B2OC(C)(C)C(C)(C)O2)cc1Cl
HCID23445107

2-(3-Chloro-4-methylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

C13H18BClO2

收率 66%

AUXILIARIES

试剂、催化剂与溶剂

4
结构：CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C
试剂HCID2733548

Bis(pinacolato)diboron

C12H24B2O4

结构：CC(C)(C)c1ccnc(-c2cc(C(C)(C)C)ccn2)c1
试剂HCID4249187

未命名化合物

结构：C1=CCCC=CCC1.C1=CCCC=CCC1.C[OH2+].C[OH2+].[Ir].[Ir]
催化剂HCID76001521

未命名化合物

结构：COC(C)(C)C
溶剂HCID15413

Methyl tert-butyl ether

C5H12O

CONDITIONS

反应条件

温度
25 °C

PROCEDURE

实验过程

General procedure C was applied to 1-chloro-2-methylbenzene 15e(51 mg, 0.4mmol). The reaction mixture was stirred at room temperature for 16hgiving a conversion of >99% (GC-MS) and 16eand17ein a 34:66mixture (1H NMR spectrum).