Tetrahydrofuran → 4,4,5,5-Tetramethyl-2-(oxolan-3-yl)-1,3,2-dioxaborolane

HRID 1491003Notes

Reaction equation

HRID 1491003 reaction equation
C1CCOC1>C1=CCCC=CCC1.C1=CCCC=CCC1.C1CCCCCCC1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.C[OH2+].C[OH2+].Cc1ccc2ccc3cccnc3c2n1.[Ir].[Ir]>CC1(C)OB(C2CCOC2)OC1(C)C

Participants

6

Reactant 1

HCID 8028Tetrahydrofuran

Product 1

HCID 111482974,4,5,5-Tetramethyl-2-(oxolan-3-yl)-1,3,2-dioxaborolaneYield 63%

Reagents, catalysts & solvents 4

HCID 2733548Bis(pinacolato)diboraneReagentHCID 49133562-Methyl-1,10-phenanthrolineReagentHCID 76001521Bis(1,5-cyclooctadiene)dimethoxydiiridiumCatalystHCID 9266CyclooctaneSolvent

Conditions

Temperature
100 °C

Sources & evidence

ORD record
ord-344d5e818c254e49a5ef8d1c0ec39e6a
Source dataset
Borylation dataset from Roche

Reaction notes

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