huagongshe.com
HRID1491132

反应详情

EQUATION

反应方程式

HRID 1491132 的结构方程式

REACTANTS

反应物

1
结构：COc1ccc(SC)cc1
HCID15885

1-Methoxy-4-(methylthio)benzene

C8H10OS

PRODUCTS

生成物

1
结构：COc1ccc(SC)c(B2OC(C)(C)C(C)(C)O2)c1
HCID132510260

未命名化合物

收率 66%

AUXILIARIES

试剂、催化剂与溶剂

4
结构：CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C
试剂HCID2733548

Bis(pinacolato)diboron

C12H24B2O4

结构：FC(F)(F)C1COB(c2ccccc2-c2ccc(-c3ccccn3)nc2)O1
试剂HCID134956623

未命名化合物

结构：C1=CCCC=CCC1.C1=CCCC=CCC1.C[OH2+].C[OH2+].[Ir].[Ir]
催化剂HCID76001521

未命名化合物

结构：Cc1ccc(C)cc1
溶剂HCID7809

p-Xylene

C8H10

CONDITIONS

反应条件

温度
55 °C

PROCEDURE

实验过程

Ligand 3f: A mixture of ortho- and meta-borylated products (92 mg, 66% yield, ortho/meta + para = >20); ortho-borylated product 4c was obtained by further purification by GPC (70 mg, 50% yield), white solid (mp. 71-73 oC)