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HRID1491135

反应详情

EQUATION

反应方程式

HRID 1491135 的结构方程式

REACTANTS

反应物

1
结构：CSc1ccc(C)cc1
HCID69334

Benzene, 1-methyl-4-(methylthio)-

C8H10S

PRODUCTS

生成物

2
结构：CSc1ccc(C)cc1B1OC(C)(C)C(C)(C)O1
HCID138983642

未命名化合物

收率 41%
结构：CSc1ccc(C)c(B2OC(C)(C)C(C)(C)O2)c1
HCID178503150

未命名化合物

收率 20%

AUXILIARIES

试剂、催化剂与溶剂

4
结构：Cc1ccnc(-c2cc(C)ccn2)c1
试剂HCID14338

4,4'-Dimethyl-2,2'-bipyridine

C12H12N2

结构：CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C
试剂HCID2733548

Bis(pinacolato)diboron

C12H24B2O4

结构：C1=CCCC=CCC1.C1=CCCC=CCC1.C[OH2+].C[OH2+].[Ir].[Ir]
催化剂HCID76001521

未命名化合物

结构：Cc1ccc(C)cc1
溶剂HCID7809

p-Xylene

C8H10

CONDITIONS

反应条件

温度
55 °C

PROCEDURE

实验过程

dtbpy: A mixture of ortho- and meta-borylated products (79 mg, 61% yield, ortho/meta + para = 2.0); meta-Isomer 5d was obtained by further purification by GPC (18 mg, 14% yield), yellow solid (mp. 85-87 oC)