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HRID1491140

反应详情

EQUATION

反应方程式

HRID 1491140 的结构方程式

REACTANTS

反应物

1
结构：CSc1ccc(-c2ccccc2)cc1
HCID11019897

4-phenylthioanisole

C13H12S

PRODUCTS

生成物

1
结构：CSc1ccc(-c2ccccc2)cc1B1OC(C)(C)C(C)(C)O1
HCID132510262

未命名化合物

收率 86%

AUXILIARIES

试剂、催化剂与溶剂

4
结构：CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C
试剂HCID2733548

Bis(pinacolato)diboron

C12H24B2O4

结构：FC(F)(F)C1COB(c2ccccc2-c2ccc(-c3ccccn3)nc2)O1
试剂HCID134956623

未命名化合物

结构：C1=CCCC=CCC1.C1=CCCC=CCC1.C[OH2+].C[OH2+].[Ir].[Ir]
催化剂HCID76001521

未命名化合物

结构：Cc1ccc(C)cc1
溶剂HCID7809

p-Xylene

C8H10

CONDITIONS

反应条件

温度
55 °C

PROCEDURE

实验过程

Ligand 3f: A mixture of ortho- and meta-borylated products (140 mg, 86% yield, ortho/meta + para = >30); ortho-borylated product 4g was obtained by further purification by GPC (128 mg, 79% yield), white solid (mp. 116-118 oC)