HRID1491164

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID13032813

3-(Methylsulfanyl)benzonitrile

C8H7NS

PRODUCTS

产物

反应SMILES：CSc1cc(C#N)ccc1B1OC(C)(C)C(C)(C)O1

HCID132510265

未命名化合物

收率 75%

AUXILIARIES

试剂、催化剂与溶剂

反应SMILES：CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C

试剂HCID2733548

Bis(pinacolato)diboron

C12H24B2O4

反应SMILES：FC(F)(F)C1COB(c2ccccc2-c2ccc(-c3ccccn3)nc2)O1

试剂HCID134956623

未命名化合物

反应SMILES：C1=CCCC=CCC1.C1=CCCC=CCC1.C[OH2+].C[OH2+].[Ir].[Ir]

催化剂HCID76001521

未命名化合物

溶剂HCID7809

p-Xylene

C8H10

CONDITIONS

反应条件

温度: 55 °C

PROCEDURE

实验过程

Ligand 3f: A mixture of ortho- and meta-borylated products (103 mg, 75% yield, ortho/meta + para = >30); ortho-borylated product 4s was obtained by further purification by GPC (74 mg, 54% yield), white solid (mp. 68-70 oC)