Triphenylphosphine → HCID 19831262, compound

HRID 1493289Notes

Reaction equation

HRID 1493289 reaction equation
[Br:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][C:11]([F:14])([F:13])[F:12].[C:15]1([P:21]([C:28]2[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=2)[C:22]2[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=2)[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1>C(#N)C>[Br-:1].[F:12][C:11]([F:14])([F:13])[CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][P+:21]([C:22]1[CH:23]=[CH:24][CH:25]=[CH:26][CH:27]=1)([C:28]1[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=1)[C:15]1[CH:16]=[CH:17][CH:18]=[CH:19][CH:20]=1

Participants

4

Reactant 2

HCID 11776TriphenylphosphineHCID 19831264HCID 19831264, compound

Product 1

HCID 19831262HCID 19831262, compound

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent

Procedure

A stirred solution of 1-bromo-10,10,10-trifluorodecane (4.75 g) and triphenylphosphine (4.53 g) in acetonitrile (100 ml) was heated under reflux for 3 days. The solution was evaporated under vacuum and the residue was washed with ether, dissolved in toluene and the solution diluted with ether to give the product as a hygroscopic solid.

Workup

  1. temperatureunder reflux for 3 days
  2. customThe solution was evaporated under vacuum
  3. washthe residue was washed with ether
  4. dissolutiondissolved in toluene
  5. additionthe solution diluted with ether

Sources & evidence

ORD record
ord-f96c336851df443f8e49a22581e15710
Source dataset
uspto-grants-1991_06
Patent number
US05021441

Reaction notes

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