Phenyl glycidyl ether → HCID 15144527, compound

HRID 1494582Notes

Reaction equation

HRID 1494582 reaction equation
[CH2:1]([O:5][C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)[CH:2]1[O:4][CH2:3]1.[SH:12][C:13]1[S:14][C:15]([SH:18])=[N:16][N:17]=1>C(O)(C)C>[C:6]1([O:5][CH2:1][CH:2]([OH:4])[CH2:3][S:12][C:13]2[S:14][C:15]([S:18][CH2:3][CH:2]([OH:4])[CH2:1][O:5][C:6]3[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=3)=[N:16][N:17]=2)[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1

Participants

4

Reactant 2

HCID 31217Phenyl glycidyl etherHCID 178418558HCID 178418558, compound

Product 1

HCID 15144527HCID 15144527, compound

Reagents, catalysts & solvents 1

HCID 3776IsopropanolSolvent

Procedure

Phenyl glycidyl ether (179.4 grams, 1.20 moles) and isopropanol (200 ml) were charged into the reaction vessel. 2,5-Dimercapto-1,3,4-thiadiazole (85 grams, 0.568 moles) was added in increments and with stirring. The reaction mixture was refluxed for 5 minutes. The solvent was stripped off by using a rotary evaporator at about 20 mm Hg and 115° C. The product solidified on cooling and was characterized by the infrared absorption bands at 3400, 3060, 2920, 1600, 1500, 1380, 1240, 1040, 750, and 690 cm-1.

Workup

  1. temperatureThe reaction mixture was refluxed for 5 minutes
  2. customa rotary evaporator at about 20 mm Hg and 115° C
  3. temperatureon cooling
  4. customwas characterized by the infrared absorption bands at 3400, 3060, 2920, 1600, 1500, 1380, 1240, 1040, 750, and 690 cm-1

Sources & evidence

ORD record
ord-e7243e5a9f9c4b6fbc048a579b5c6db2
Source dataset
uspto-grants-1991_06
Patent number
US05026865

Reaction notes

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