Propanal → HCID 86658990, compound

HRID 1500169Notes

Reaction equation

HRID 1500169 reaction equation
[N+:1](/[CH:4]=[CH:5]/[CH2:6][CH2:7][C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1)([O-:3])=[O:2].[CH:14](=[O:17])[CH2:15][CH3:16].CC(O)C>CCCCCC>[CH3:16][C@@H:15]([C@@H:5]([CH2:4][N+:1]([O-:3])=[O:2])[CH2:6][CH2:7][C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1)[CH:14]=[O:17]

Participants

5

Reactant 3

HCID 527PropanalHCID 3776IsopropanolHCID 10943005HCID 10943005, compound

Product 1

HCID 86658990HCID 86658990, compound

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent

Procedure

The title compound was prepared from (E)-(4-nitrobut-3-enyl)benzene and propionaldehyde according to general procedure. The enantiomeric excess was determined by HPLC with Chiralpak AD-H column at 210 nm (2-propanol:hexane=2:98), 1 mL/min, tmajor=15.4 min, tminor=14.4 min, the diastereomeric ratio was determined by

Sources & evidence

ORD record
ord-2c52091274254c79b309b1121fbc3531
Source dataset
uspto-grants-2015_12
Patent number
US09206090B2

Reaction notes

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