zinc(II)iodide → HCID 178506620, compound

HRID 1504395Notes

Reaction equation

HRID 1504395 reaction equation
[I-:1].[Zn+2:2].[I-].[C@@H:4]12[O:10][C@@H:7]([CH2:8][CH2:9]1)[CH2:6][C@H:5]2[CH2:11]O>C1COCC1>[I-:1].[C@@H:4]12[O:10][C@@H:7]([CH2:8][CH2:9]1)[CH2:6][C@H:5]2[CH2:11][Zn+:2]

Participants

4

Reactant 2

HCID 9883512zinc(II)iodideHCID 1361430413118-78-0

Product 1

HCID 178506620HCID 178506620, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

The title compound was prepared in an analogous manner to tetrahydro-2H-pyran-4-yl)zinc(II) iodide except that (1R,2S,4S)-7-oxabicyclo[2.2.1]heptan-2-ylmethanol was used instead of tetrahydro-2H-pyran-4-ol in Step 1 to afford a 0.15M solution of ((1R,2R,4S)-7-oxabicyclo[2.2.1]heptan-2-ylmethyl)zinc(II) iodide in THF.

Sources & evidence

ORD record
ord-d8058427b9aa43e1bc21671c5e5022c0
Source dataset
uspto-grants-2015_12
Patent number
US09212182B2

Reaction notes

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