HCID 178424007, compound → 7-Methylbenzo[d]thiazole

HRID 1507526Notes

Reaction equation

HRID 1507526 reaction equation
[CH3:1][C:2]1[C:10]2[S:9][C:8](S)=[N:7][C:6]=2[CH:5]=[CH:4][CH:3]=1>C(O)(=O)C.[Fe]>[CH3:1][C:2]1[C:10]2[S:9][CH:8]=[N:7][C:6]=2[CH:5]=[CH:4][CH:3]=1

Participants

4

Reactant 1

HCID 178424007HCID 178424007, compound

Product 1

HCID 156550227-Methylbenzo[d]thiazole

Reagents, catalysts & solvents 2

HCID 23925IronCatalystHCID 176Acetic AcidSolvent

Procedure

Following the same procedure as in step 2 of Example 337 using 7-methyl-1,3-benzothiazole-2-thiol (3.8 g, 20.96 mmol, 1.00 equiv) and iron powder (9.28 g, 171.85 mmol, 8.20 equiv) in acetic acid (24 mL) as a yellow oil.

Sources & evidence

ORD record
ord-44996eb4b7b4470eaa42aa80d52ddc8c
Source dataset
uspto-grants-2015_12
Patent number
US09221809B2

Reaction notes

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