Hydrochloric Acid → HCID 9989459, compound
Reaction equation
[CH2:1]=[CH:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]Br.[N:10](N)([CH3:12])[CH3:11].Cl.[OH-].[Na+]>CCOCC>[CH2:1]=[CH:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][N:10]([CH3:12])[CH3:11]Participants
Reactant 4
Product 1
Reagents, catalysts & solvents 1
Procedure
HOSiPcOSi(CH3)2(CH2)8N(CH3)2 Compound XXII A solution of CH2═CH(CH2)6Br, (CH3)2NNH2 and ether was stirred, the reaction mixture was worked up with HCl, NaNO3, and NaOH, and the resulting CH2═CH(CH2)6N(CH3)2 was isolated and distilled. A solution of this compound, (CH3)2SiHCl, CHCl3, H2PtCl6xH2O and isopropanol was warmed and the CH3OSi(CH3)2(CH2)8N(CH3)2—HCl formed was isolated. Next, a suspension of this intermediate, CH3SiPcOH and pyridine was partially distilled, and the CH3SiPcOSi(CH3)2(CH2)8N(CH3)2 obtained was isolated and recrystallized. Finally, a solution of this compound and CH2Cl2 was irradiated with light and the product was isolated, chromatographed, and recrystallized: MS-HRFAB exact mass, m/z: calculated for C44H45N9O2Si2 (M+H)+, 788.3313; found, 788.3300, 788.3290.
Sources & evidence
- ORD record
- ord-5acf0ab7494141e3b2693c0527bdf6d4
- Source dataset
- uspto-grants-2012_07
- Patent number
- US08211883B2
Reaction notes
Loading…