HRID1522960

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID8857

Ethyl acetate

C4H8O2

HCID13087229

N-phenyl-(1,1'-biphenyl)-4-amine

C18H15N

HCID18942624

3-Bromo-9-phenyl-9H-carbazole

C18H12BrN

PRODUCTS

生成物

结构：c1ccc(-c2ccc(N(c3ccccc3)c3ccc4c(c3)c3ccccc3n4-c3ccccc3)cc2)cc1

HCID71059317

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID8058

n-Hexane

C6H14

PROCEDURE

实验过程

The Rf values of the objective substance, 3-bromo-9-phenyl-9H-carbazole, and N-phenyl-N-(4-phenylphenyl)amine were respectively 0.65, 0.73, and 0.54, which were obtained by silica gel thin layer chromatography (TLC) (with a developing solvent containing ethyl acetate and hexane in a 1:5 ratio).

WORKUP

后处理

customwhich were obtained by silica gel thin layer chromatography (TLC) (with a developing solvent

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-47fc3921fefd422ebef6b626a2d88847
来源数据集: uspto-grants-2015_07
DOI: 10.6084/m9.figshare.5104873.v1
专利: US09079855B2
来源说明: uspto-grants-2015_07

反应 SMILES

Br[C:2]1[CH:3]=[CH:4][C:5]2[N:6]([C:15]3[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=3)[C:7]3[C:12]([C:13]=2[CH:14]=1)=[CH:11][CH:10]=[CH:9][CH:8]=3.[C:21]1([NH:27][C:28]2[CH:33]=[CH:32][C:31]([C:34]3[CH:39]=[CH:38][CH:37]=[CH:36][CH:35]=3)=[CH:30][CH:29]=2)[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=1.C(OCC)(=O)C>CCCCCC>[C:21]1([N:27]([C:28]2[CH:33]=[CH:32][C:31]([C:34]3[CH:35]=[CH:36][CH:37]=[CH:38][CH:39]=3)=[CH:30][CH:29]=2)[C:2]2[CH:3]=[CH:4][C:5]3[N:6]([C:7]4[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=4)[C:15]4[C:16]([C:13]=3[CH:14]=2)=[CH:17][CH:18]=[CH:19][CH:20]=4)[CH:22]=[CH:23][CH:24]=[CH:25][CH:26]=1