Ethyl Acetate → N-phenyl-N-(4-phenylphenyl)-N-(9-phenyl-9H-carbazol-3-yl)amine

HRID 1522960Notes

Reaction equation

HRID 1522960 reaction equation
Br[C:2]1[CH:3]=[CH:4][C:5]2[N:6]([C:15]3[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=3)[C:7]3[C:12]([C:13]=2[CH:14]=1)=[CH:11][CH:10]=[CH:9][CH:8]=3.[C:21]1([NH:27][C:28]2[CH:33]=[CH:32][C:31]([C:34]3[CH:39]=[CH:38][CH:37]=[CH:36][CH:35]=3)=[CH:30][CH:29]=2)[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=1.C(OCC)(=O)C>CCCCCC>[C:21]1([N:27]([C:28]2[CH:33]=[CH:32][C:31]([C:34]3[CH:35]=[CH:36][CH:37]=[CH:38][CH:39]=3)=[CH:30][CH:29]=2)[C:2]2[CH:3]=[CH:4][C:5]3[N:6]([C:7]4[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=4)[C:15]4[C:16]([C:13]=3[CH:14]=2)=[CH:17][CH:18]=[CH:19][CH:20]=4)[CH:22]=[CH:23][CH:24]=[CH:25][CH:26]=1

Participants

5

Reactant 3

HCID 8857Ethyl AcetateHCID 13087229N-phenyl-(1,1'-biphenyl)-4-amineHCID 189426243-Bromo-9-phenylcarbazole

Product 1

HCID 71059317N-phenyl-N-(4-phenylphenyl)-N-(9-phenyl-9H-carbazol-3-yl)amine

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent

Procedure

The Rf values of the objective substance, 3-bromo-9-phenyl-9H-carbazole, and N-phenyl-N-(4-phenylphenyl)amine were respectively 0.65, 0.73, and 0.54, which were obtained by silica gel thin layer chromatography (TLC) (with a developing solvent containing ethyl acetate and hexane in a 1:5 ratio).

Workup

  1. customwhich were obtained by silica gel thin layer chromatography (TLC) (with a developing solvent

Sources & evidence

ORD record
ord-47fc3921fefd422ebef6b626a2d88847
Source dataset
uspto-grants-2015_07
Patent number
US09079855B2

Reaction notes

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