Potassium Cation → 3-(Pyridin-2-yl)benzaldehyde

HRID 155522Notes

Reaction equation

HRID 155522 reaction equation
[Br:1][c:2]1[cH:3][c:4]([CH:5]=[O:6])[cH:7][cH:8][cH:9]1.[CH2:17]([Sn:18]([CH2:19][CH2:20][CH2:21][CH3:28])([c:22]1[n:23][cH:24][cH:25][cH:26][cH:27]1)[CH2:29][CH2:30][CH2:31][CH3:32])[CH2:33][CH2:34][CH3:35].[CH3:10][c:11]1[cH:12][cH:13][cH:14][cH:15][cH:16]1.[CH3:79][CH2:80][O:81][C:82](=[O:83])[CH3:84].[F-:36].[K+:37].[OH2:85].[Pd:38]([Cl:39])[Cl:40].[c:41]1([P:42]([c:43]2[cH:44][cH:45][cH:46][cH:47][cH:48]2)[c:49]2[cH:50][cH:51][cH:52][cH:53][cH:54]2)[cH:55][cH:56][cH:57][cH:58][cH:59]1.[c:60]1([P:61]([c:62]2[cH:63][cH:64][cH:65][cH:66][cH:67]2)[c:68]2[cH:69][cH:70][cH:71][cH:72][cH:73]2)[cH:74][cH:75][cH:76][cH:77][cH:78]1>>[c:2]1(-[c:22]2[n:23][cH:24][cH:25][cH:26][cH:27]2)[cH:3][c:4]([CH:5]=[O:6])[cH:7][cH:8][cH:9]1

Participants

10

Reactant 9

HCID 813Potassium CationHCID 962WaterHCID 1140TolueneHCID 8857Ethyl AcetateHCID 11776Triphenylphosphine2×HCID 24290Palladium ChlorideHCID 28179Fluoride IonHCID 765833-BromobenzaldehydeHCID 6077842-(Tributylstannyl)pyridine

Product 1

HCID 37100393-(Pyridin-2-yl)benzaldehyde

Sources & evidence

ORD record
ord-4017c41dfe76450ba75a2904f0d33ce4
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (9/10)

Reaction notes

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