Potassium Cation → 3,4-dihydro-3,3-dimethyl-6-methylthio-2(1H)-quinolinone

HRID 1556685Notes

Reaction equation

HRID 1556685 reaction equation
[C:24](=[O:25])([O-:26])[O-:27].[CH2:1]([SiH:2]([CH2:3][CH3:4])[CH2:5][CH3:6])[CH3:7].[CH3:8][C:9]1([CH3:23])[C:10](=[O:22])[NH:11][c:12]2[cH:13][cH:14][c:15]([S:20][CH3:21])[cH:16][c:17]2[C:18]1=[O:19].[K+:28].[K+:29].[OH:30][C:31]([C:32]([F:33])([F:34])[F:35])=[O:36]>>[CH3:8][C:9]1([CH3:23])[C:10](=[O:22])[NH:11][c:12]2[cH:13][cH:14][c:15]([S:20][CH3:21])[cH:16][c:17]2[CH2:18]1

Participants

6

Reactant 5

HCID 813Potassium Cation2×HCID 6422Trifluoroacetic acidHCID 12052TriethylsilaneHCID 19660Carbonate IonHCID 225957253,3-dimethyl-6-methylthio-2,4(1H,3H)-quinolinedione

Product 1

HCID 225957533,4-dihydro-3,3-dimethyl-6-methylthio-2(1H)-quinolinone

Sources & evidence

ORD record
ord-a48fc20b7e6943fe83695be041b2ed25
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (1/10)

Reaction notes

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