Chloroform → 1-(6-Chloropyridin-3-yl)pent-4-ene-1,2,2-tricarbonitrile

HRID 1558530Notes

Reaction equation

HRID 1558530 reaction equation
[CH2:14]([CH:15]=[CH2:16])[Cl:17].[CH3:18][Si:19]([CH3:20])([CH3:21])[C:22]#[N:23].[CH:80]([Cl:81])([Cl:82])[Cl:83].[Cl:1][c:2]1[cH:3][cH:4][c:5]([CH:8]=[C:9]([C:10]#[N:11])[C:12]#[N:13])[cH:6][n:7]1.[O:26]=[C:27]([CH:28]=[CH:29][c:30]1[cH:31][cH:32][cH:33][cH:34][cH:35]1)[CH:36]=[CH:37][c:38]1[cH:39][cH:40][cH:41][cH:42][cH:43]1.[O:44]=[C:45]([CH:46]=[CH:47][c:48]1[cH:49][cH:50][cH:51][cH:52][cH:53]1)[CH:54]=[CH:55][c:56]1[cH:57][cH:58][cH:59][cH:60][cH:61]1.[O:62]=[C:63]([CH:64]=[CH:65][c:66]1[cH:67][cH:68][cH:69][cH:70][cH:71]1)[CH:72]=[CH:73][c:74]1[cH:75][cH:76][cH:77][cH:78][cH:79]1.[O:84]1[CH2:85][CH2:86][CH2:87][CH2:88]1.[Pd:24].[Pd:25]>>[Cl:1][c:2]1[cH:3][cH:4][c:5]([CH:8]([C:9]([C:10]#[N:11])([C:12]#[N:13])[CH2:14][CH:15]=[CH2:16])[C:22]#[N:23])[cH:6][n:7]1

Participants

8

Reactant 7

HCID 6212ChloroformHCID 7850Allyl chlorideHCID 8028TetrahydrofuranHCID 23938Palladium2×HCID 82115Trimethylsilyl cyanideHCID 95417Dibenzylidene acetone3×HCID 22185757HCID 22185757, compound

Product 1

HCID 221857521-(6-Chloropyridin-3-yl)pent-4-ene-1,2,2-tricarbonitrile

Sources & evidence

ORD record
ord-5eb014cac57a44e4b71f35fa3ff7b024
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (1/10)

Reaction notes

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