Bromide ion → 4-(Benzyloxy)-1-bromo-2-vinylbenzene

HRID 1561269Notes

Reaction equation

HRID 1561269 reaction equation
[Br-:42].[CH2:25]([c:26]1[cH:27][cH:28][cH:29][cH:30][cH:31]1)[O:32][c:33]1[cH:34][cH:35][c:36]([Br:41])[c:37]([CH:38]=[O:39])[cH:40]1.[CH2:63]1[O:64][CH2:65][CH2:66][CH2:67]1.[CH3:19][C:20]([CH3:21])([O-:22])[CH3:23].[CH3:43][P+:44]([c:45]1[cH:46][cH:47][cH:48][cH:49][cH:50]1)([c:51]1[cH:52][cH:53][cH:54][cH:55][cH:56]1)[c:57]1[cH:58][cH:59][cH:60][cH:61][cH:62]1.[K+:24].[O:1]1[CH2:2][CH2:18][O:17][CH2:16][CH2:15][O:14][CH2:13][CH2:12][O:11][CH2:10][CH2:9][O:8][CH2:7][CH2:6][O:5][CH2:4][CH2:3]1>>[CH2:2]=[CH:38][c:37]1[c:36]([Br:41])[cH:35][cH:34][c:33]([O:32][CH2:25][c:26]2[cH:27][cH:28][cH:29][cH:30][cH:31]2)[cH:40]1

Participants

8

Reactant 7

HCID 259Bromide ionHCID 813Potassium CationHCID 8028TetrahydrofuranHCID 2855718-Crown-6HCID 74506TriphenylmethylphosphoniumHCID 45749132-Methylpropan-2-olateHCID 108700245-(Benzyloxy)-2-bromobenzaldehyde

Product 1

HCID 692072164-(Benzyloxy)-1-bromo-2-vinylbenzene

Sources & evidence

ORD record
ord-6b2719849ca54959814140ff51256262
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (1/10)

Reaction notes

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