Chloride → 7-bromo-4-(1-ethoxyvinyl)-2H-chromen-2-one

HRID 1564146Notes

Reaction equation

HRID 1564146 reaction equation
[Br:1][c:2]1[cH:3][cH:4][c:5]2[c:6]([O:13][S:14]([C:15]([F:16])([F:17])[F:18])(=[O:19])=[O:20])[cH:7][c:8](=[O:12])[o:9][c:10]2[cH:11]1.[CH2:21]([Sn:22]([CH2:23][CH2:24][CH2:25][CH3:31])([C:26](=[CH2:27])[O:28][CH2:29][CH3:30])[CH2:32][CH2:33][CH2:34][CH3:35])[CH2:36][CH2:37][CH3:38].[Cl-:39].[Li+:40].[O:41]1[CH2:42][CH2:43][O:44][CH2:45][CH2:46]1>>[Br:1][c:2]1[cH:3][cH:4][c:5]2[c:6]([C:26](=[CH2:27])[O:28][CH2:29][CH3:30])[cH:7][c:8](=[O:12])[o:9][c:10]2[cH:11]1

Participants

6

Reactant 5

HCID 312ChlorideHCID 28486Lithium ionHCID 312751,4-DioxaneHCID 619414Stannane, tributyl(1-ethoxyethenyl)-HCID 194269487-bromo-2-oxo-2H-chromen-4-yl trifluoromethanesulfonate

Product 1

HCID 233702047-bromo-4-(1-ethoxyvinyl)-2H-chromen-2-one

Sources & evidence

ORD record
ord-2c3605591b8e46adacc606181bd7d229
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (1/10)

Reaction notes

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