HRID1567760

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID6342

Acetonitrile

C2H3N

HCID7834

1,2-Epoxybutane

C4H8O

HCID11776

Triphenylphosphine

C18H15P

HCID10987703

5-((tert-Butyldimethylsilyl)oxy)pentanal

C11H24O2Si

HCID66619759

未命名化合物

PRODUCTS

生成物

结构：CCOC(=O)C=Cc1c(C=CCCCCO[Si](C)(C)C(C)(C)C)cccc1OCCCC(=O)OCC

HCID66619835

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-ea6d0e899a21400c8878f5a19b75a496
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (1/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (1/10)

反应 SMILES

[C:44]([CH3:45])([CH3:46])([CH3:47])[Si:48]([O:49][CH2:50][CH2:51][CH2:52][CH2:53][CH:54]=[O:55])([CH3:56])[CH3:57].[CH2:1]([CH3:2])[O:3][C:4]([CH2:5][CH2:6][CH2:7][O:8][c:9]1[c:10]([CH:17]=[CH:18][C:19](=[O:20])[O:21][CH2:22][CH3:23])[c:11]([CH2:15][Br:16])[cH:12][cH:13][cH:14]1)=[O:24].[CH3:58][C:59]#[N:60].[O:61]1[CH:62]([CH2:63][CH3:64])[CH2:65]1.[c:25]1([P:26]([c:27]2[cH:28][cH:29][cH:30][cH:31][cH:32]2)[c:33]2[cH:34][cH:35][cH:36][cH:37][cH:38]2)[cH:39][cH:40][cH:41][cH:42][cH:43]1>>[CH2:1]([CH3:2])[O:3][C:4]([CH2:5][CH2:6][CH2:7][O:8][c:9]1[c:10]([CH:17]=[CH:18][C:19](=[O:20])[O:21][CH2:22][CH3:23])[c:11]([CH:15]=[CH:54][CH2:53][CH2:52][CH2:51][CH2:50][O:49][Si:48]([C:44]([CH3:45])([CH3:46])[CH3:47])([CH3:56])[CH3:57])[cH:12][cH:13][cH:14]1)=[O:24]