HCID 20436125, compound → HCID 53884118, compound

HRID 1577942Notes

Reaction equation

HRID 1577942 reaction equation
CC([O-])(C)C.[K+].[CH2:7]([CH:9]([CH2:15][CH2:16][CH2:17][CH3:18])[CH:10]=[N:11][CH2:12][CH:13]=[CH2:14])[CH3:8]>O1CCCC1>[CH:12](=[N:11][CH:10]=[C:9]([CH2:7][CH3:8])[CH2:15][CH2:16][CH2:17][CH3:18])[CH2:13][CH3:14]

Participants

4

Reactant 2

HCID 20436125HCID 20436125, compoundHCID 23665647Potassium tert-butoxide

Product 1

HCID 53884118HCID 53884118, compoundYield 85.2%

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

The procedure is carried out as described in Example 1 with the use however in this case of 10 g of potassium tert-butylate, 800 g (4.79 mols) of (2-ethylhexylidene)-allylamine and 600 ml of tetrahydrofuran. After a reaction time of 2 hours at 35° C., there is obtained 682 g (4.08 mols) of N-propylidene-(2-ethylhexen-1-yl-amine), corresponding to a yield of 85.2% of theory (isomeric mixture in the weight ratio of 55:45); b.p. 53°-56° C./1 Torr; nD20 =1.4698.

Sources & evidence

ORD record
ord-747e8f0840cb4c91827679d8339e75ae
Source dataset
uspto-grants-1981_09
Patent number
US04289905

Reaction notes

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