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HRID1578498

反应详情

EQUATION

反应方程式

HRID 1578498 的结构方程式

REACTANTS

反应物

3
结构：O=C(OO)c1cccc(Cl)c1
HCID70297

Benzenecarboperoxoic acid, 3-chloro-

C7H5ClO3

结构：Cn1nc(S(C)(=O)=O)c(=O)c2ccccc21
HCID12421487

3-(Methanesulfonyl)-1-methylcinnolin-4(1H)-one

C10H10N2O3S

结构：Cn1nc(S(C)=O)c(=O)c2ccc(Cl)cc21
HCID21559126

未命名化合物

PRODUCTS

生成物

1
结构：Cn1nc(S(C)(=O)=O)c(=O)c2ccc(Cl)cc21
HCID21559129

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：ClC(Cl)Cl
溶剂HCID6212

Chloroform

CHCl3

PROCEDURE

实验过程

This was prepared by oxidizing a solution of 10 g of 7-chloro-1-methyl-3-(methylsulfinyl)-4(1H)-cinnolinone in 500 ml of CHCl3 with 7.5 g of m-chloroperbenzoic acid in analogous fashion to 1-methyl-3-(methylsulfonyl)-4(1H)-cinnolinone. The material was recrystallized from CH3CN, m.p. 270°-72°; yield 7.5 g (71%).

WORKUP

后处理

  1. customThis was prepared
  2. customThe material was recrystallized from CH3CN, m.p. 270°-72°