2,2,2-Trifluoroethanol → HCID 21558588, compound

HRID 1578727Notes

Reaction equation

HRID 1578727 reaction equation
Cl[C:2]1[C:10]2[NH:9][C:8]([C:11]([F:17])([F:16])[C:12]([F:15])([F:14])[F:13])=[N:7][C:6]=2[C:5]([N+:18]([O-:20])=[O:19])=[CH:4][C:3]=1[C:21]#[N:22].[Na].[F:24][C:25]([F:29])([F:28])[CH2:26][OH:27]>>[F:24][C:25]([F:29])([F:28])[CH2:26][O:27][C:2]1[C:10]2[NH:9][C:8]([C:11]([F:17])([F:16])[C:12]([F:15])([F:14])[F:13])=[N:7][C:6]=2[C:5]([N+:18]([O-:20])=[O:19])=[CH:4][C:3]=1[C:21]#[N:22]

Participants

4

Reactant 3

HCID 64092,2,2-TrifluoroethanolHCID 5360545SodiumHCID 135783935HCID 135783935, compound

Product 1

HCID 21558588HCID 21558588, compound

Procedure

4-Chloro-7-nitro-5-cyano-2-pentafluoroethylbenzimidazole is reacted with the sodium salt of 2,2,2,-trifluoroethanol to obtain 4-(2,2,2-trifluoroethoxy)-7-nitro-5-cyano-2-pentafluoroethylbenzimidazole, m.w., 404.2.

Sources & evidence

ORD record
ord-edd715fc41c54a83a83d4e0340837e25
Source dataset
uspto-grants-1976_02
Patent number
US03939166

Reaction notes

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