Sodium Carbonate → Triallyl phosphate

HRID 1578832Notes

Reaction equation

HRID 1578832 reaction equation
C(=O)([O-])[O-:2].[Na+].[Na+].C(=O)(O)[O-].[Na+].[Cr](O[Cr]([O-])(=O)=O)([O-])(=O)=O.[K+].[K+].[P:23]([O:32][CH2:33][CH:34]=[CH2:35])([O:28][CH2:29][CH:30]=[CH2:31])[O:24][CH2:25][CH:26]=[CH2:27]>O=O.O>[P:23]([O:28][CH2:29][CH:30]=[CH2:31])([O:32][CH2:33][CH:34]=[CH2:35])([O:24][CH2:25][CH:26]=[CH2:27])=[O:2]

Participants

7

Reactant 4

HCID 10340Sodium CarbonateHCID 24502Potassium DichromateHCID 66893Phosphorous acid, tri-2-propenyl esterHCID 516892Sodium Bicarbonate

Product 1

HCID 15390Triallyl phosphateYield 96%

Reagents, catalysts & solvents 2

HCID 962WaterSolventHCID 977OxygenSolvent

Procedure

To 10 ml. of an aqueous solution containing 0.5 g. of sodium carbonate and 0.25 g. of sodium bicarbonate there is added a solution of 1.0 g. of potassium dichromate in 50 ml. of water, then 60 ml. of triallyl phosphite. The resulting mixture is stirred at 25°-30°C while passing in oxygen for eight hours. The aqueous layer is removed, leaving a 96% yield of substantially pure triallyl phosphate.

Workup

  1. additionof an aqueous solution containing 0.5 g
  2. customThe aqueous layer is removed

Sources & evidence

ORD record
ord-3d4fcfb61293495fb01615714ee984b2
Source dataset
uspto-grants-1976_02
Patent number
US03939229

Reaction notes

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