Hydrogen Peroxide → HCID 86732863, compound

HRID 1579212Notes

Reaction equation

HRID 1579212 reaction equation
[CH3:1][N:2]([CH2:4][C:5]([N:7]1[CH2:12][C:11](=[CH:13][C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[C:10]2=[N:20][N:21]([CH3:29])[CH:22]([C:23]3[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=3)[CH:9]2[CH2:8]1)=[O:6])[CH3:3].[OH:30]O>C(O)(=O)C>[CH3:3][N:2]([CH2:4][C:5]([N:7]1[CH2:12][C:11](=[CH:13][C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[C:10]2=[N+:20]([O-:30])[N:21]([CH3:29])[CH:22]([C:23]3[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=3)[CH:9]2[CH2:8]1)=[O:6])[CH3:1]

Participants

4

Reactant 2

HCID 784Hydrogen PeroxideHCID 53710559HCID 53710559, compound

Product 1

HCID 86732863HCID 86732863, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

A solution of the free base of the product of Example 3 in acetic acid is treated with an equivalent quantity of 30% hydrogen peroxide and the solution then heated at 80°-90° for 1 hour and cooled. The solvent is then removed on a rotary evaporator at reduced pressure to yield the title compound.

Workup

  1. temperaturethe solution then heated at 80°-90° for 1 hour
  2. temperaturecooled
  3. customThe solvent is then removed on a rotary evaporator at reduced pressure

Sources & evidence

ORD record
ord-13f2a80106d64503b9701e1bce133dfd
Source dataset
uspto-grants-1976_01
Patent number
US03931169

Reaction notes

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