HRID157962

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID923

Sodium ion

Na+

HCID1140

Toluene

C7H8

HCID8028

Tetrahydrofuran

C4H8O

HCID11776

Triphenylphosphine

C18H15P

4 次

HCID23938

Palladium

HCID166653

Hydride

H-

HCID3435097

Triisopropylsilanethiol

C9H22SSi

结构：CCOC(=O)C1CCc2ccc(OS(=O)(=O)C(F)(F)F)cc2O1

HCID86652954

未命名化合物

PRODUCTS

生成物

结构：CCOC(=O)C1CCc2ccc(S[Si](C(C)C)(C(C)C)C(C)C)cc2O1

HCID66878159

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-6159d256c6ca43aab70590f73e28b9bb
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (9/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (9/10)

反应 SMILES

[CH2:44]1[O:45][CH2:46][CH2:47][CH2:48]1.[CH3:37][c:38]1[cH:39][cH:40][cH:41][cH:42][cH:43]1.[CH:3]([CH3:4])([CH3:5])[Si:6]([SH:7])([CH:8]([CH3:9])[CH3:10])[CH:11]([CH3:12])[CH3:13].[F:14][C:15]([F:16])([F:17])[S:18]([O:19][c:20]1[cH:21][cH:22][c:23]2[c:28]([cH:29]1)[O:27][CH:26]([C:30](=[O:31])[O:32][CH2:33][CH3:34])[CH2:25][CH2:24]2)(=[O:35])=[O:36].[H-:2].[Na+:1].[Pd:49].[c:107]1([P:108]([c:109]2[cH:110][cH:111][cH:112][cH:113][cH:114]2)[c:115]2[cH:116][cH:117][cH:118][cH:119][cH:120]2)[cH:121][cH:122][cH:123][cH:124][cH:125]1.[c:50]1([P:51]([c:52]2[cH:53][cH:54][cH:55][cH:56][cH:57]2)[c:58]2[cH:59][cH:60][cH:61][cH:62][cH:63]2)[cH:64][cH:65][cH:66][cH:67][cH:68]1.[c:69]1([P:70]([c:71]2[cH:72][cH:73][cH:74][cH:75][cH:76]2)[c:77]2[cH:78][cH:79][cH:80][cH:81][cH:82]2)[cH:83][cH:84][cH:85][cH:86][cH:87]1.[c:88]1([P:89]([c:90]2[cH:91][cH:92][cH:93][cH:94][cH:95]2)[c:96]2[cH:97][cH:98][cH:99][cH:100][cH:101]2)[cH:102][cH:103][cH:104][cH:105][cH:106]1>>[CH:3]([CH3:4])([CH3:5])[Si:6]([S:7][c:20]1[cH:21][cH:22][c:23]2[c:28]([cH:29]1)[O:27][CH:26]([C:30](=[O:31])[O:32][CH2:33][CH3:34])[CH2:25][CH2:24]2)([CH:8]([CH3:9])[CH3:10])[CH:11]([CH3:12])[CH3:13]