Azobisisobutyronitrile → HCID 86587239, compound

HRID 1582512Notes

Reaction equation

HRID 1582512 reaction equation
[C:1]1(=[O:7])[O:6][C:4](=[O:5])[CH:3]=[CH:2]1.[F:8][CH:9]([CH2:23][C:24]([F:27])([F:26])[F:25])[C:10]([O:13][C:14]([CH:16]1[CH2:21][CH:20]2[CH2:22][CH:17]1[CH:18]=[CH:19]2)=[O:15])([F:12])[F:11].[F:28][CH:29]1[CH:40]=[CH:39][CH:38]=[C:37]([F:41])[C:30]1([CH3:42])[CH2:31][C:32](=[CH2:36])[C:33]([O-:35])=[O:34].CC(N=NC(C#N)(C)C)(C#N)C>O1CCCC1>[C:4]1(=[O:5])[O:6][C:1](=[O:7])[CH:2]=[CH:3]1.[F:8][CH:9]([CH2:23][C:24]([F:25])([F:26])[F:27])[C:10]([O:13][C:14]([CH:16]1[CH2:21][CH:20]2[CH2:22][CH:17]1[CH:18]=[CH:19]2)=[O:15])([F:12])[F:11].[F:41][CH:37]1[CH:38]=[CH:39][CH:40]=[C:29]([F:28])[C:30]1([CH3:42])[CH2:31][C:32](=[CH2:36])[C:33]([O-:35])=[O:34]

Participants

6

Reactant 4

HCID 6547AzobisisobutyronitrileHCID 7923Maleic AnhydrideHCID 86587194HCID 86587194, compoundHCID 86587195HCID 86587195, compound

Product 1

HCID 86587239HCID 86587239, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

To 20 mL of tetrahydrofuran was added 10 mmole of maleic anhydride, 10 mmole of hexafluorobutyl-5-norbornene-2-carboxylate, 80 mmole of 2,6-difluoro-1-methylbenzylacrylate and 0.3 g of AIBN, and the resulting solution was reacted at about 65° C. for about 10 hours.

Workup

  1. customthe resulting solution was reacted at about 65° C. for about 10 hours

Sources & evidence

ORD record
ord-a0abf193a9b6418a8f018c5a1a0dfd35
Source dataset
uspto-grants-2004_05
Patent number
US06737217B2

Reaction notes

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